Phase-separation of miscible liquids in a centrifuge

Phase-separation of miscible liquids in a centrifuge

We show that a liquid mixture in the thermodynamically stable homogeneous phase can undergo a phaseseparation transition when rotated at sufficiently high frequency ω. This phase-transition is different from the usual case where two liquids are immiscible or where the slow sedimentation process of one component (e.g. a polymer) is accelerated due to centrifugation. For a binary mixture, the mai...

Temperature Gradients Induced Phase Separation in a Miscible Polymer Solution.

Jiro Kumaki,1 Takeji Hashimoto,1,2 and Steve Granick3 1Hashimoto Polymer Phasing Project, ERATO, JRDC, Keihanna Plaza, Seika, Kyoto 619-02, Japan 2Division of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 606-01, Japan 3Department of Materials Science and Engineering, University of Illinois, Urbana, Illinois 61801 (Received 27 February 1996) Phase separation occurre...

Transient surface tension in miscible liquids.

Evidence of the existence of a transient surface tension between two miscible fluid phases is given. This is done by making use of a density matched free of gravity perturbations, binary liquid of isobutyric acid and water, which presents a miscibility gap and is studied by light scattering. The experiment is performed very near the critical point of the binary liquid, where the diffusion of ph...

Phase separation in mixtures of ionic liquids and water.

The phase separation of ionic liquids (ILs) in water is studied by laser light scattering (LLS). For the ILs with longer alkyl chains, such as [C(8)mim]BF(4) and [C(6)mim]BF(4) (mim = methylimidazolium), macroscopic phase separation occurs in the mixture with water. LLS also reveals the coexistence of the mesoscopic phase, the size of which is in the order of 100-800 nm. In aqueous mixtures of ...

Simulation of Phase Separation in Quiescent and Sheared Liquids